Reserve directly with us
Up to 10% cheaper
than with Booking.com
Check rooms and rates
From152US$ /night
Check-in
06Nov2025Select date
Check-out
07Nov2025Select date
Rooms and Guests2 Guests, 1 Room
Key details

About the Hotel

Via E. S. Piccolomini 135, Siena, Italy, 53100

Historic Villa Accommodation

Hotel Palazzo Di Valli occupies an 18th-century villa that once belonged to the Piccolomini family. The 11 rooms feature classic Tuscan decor with parquet floors, free Wi-Fi, air conditioning, and minibars. Some rooms include frescoed ceilings and private terraces with views of Siena and the surrounding hills. All bathrooms have walk-in showers, bidets, and free toiletries.

Breakfast and Garden Terrace

Breakfast is served on the large terrace overlooking the private park. Guests can enjoy drinks in the shade of pear trees. The property does not have a restaurant but is surrounded by local dining options including Tony's Pizza and traditional Tuscan trattories within walking distance.

Private Park and Activities

The hotel sits within a large private park with ancient olive trees. Activities include exclusive walking tours, cooking classes featuring pici pasta and bruschetta, truffle hunting experiences at Loghi Farm, horseback riding along Via Francigena paths, and guided tours to Chianti wineries and San Gimignano. Wine and olive oil tastings are available on-site.

Siena Access and Transport

Located 3.5 km from Siena's center near Porta Romana, the hotel is an 800-meter walk from the city walls. Bus #7 stops outside the property, providing access to Piazza del Campo in minutes. Peretola Airport is 90 km away. Private parking is available, as private vehicles are prohibited within Siena's city walls.

Guest Services and Tours

The staff assists with tour bookings, bus tickets, and local recommendations. Services include guided tours to Montalcino Brunello wineries, Pienza cheese factories, Volterra alabaster workshops, and Chianti Classico vineyards. Truffle hunting experiences include product tastings and worldwide shipping of purchased items. Cooking classes require a minimum of 4 participants.

View all

Choose the Room

From cosy doubles to spacious family suites – all with flexible options, breakfast, and exclusive deals.
Single Room
2 persons
12 m² 
1 Single bed
Shower
Heating
Classic Double Room
2 persons
17 m² 
1 King-size bed
Shower
Heating
Superior Double Room
2 persons
24 m² 
1 King-size bed
Shower
Heating
Comfort Double Room
2 persons
20 m² 
1 King-size bed
Shower
Heating
Click button to see more rooms
Show all rooms
Show all roomsLess

Check Dates & Room Rates

See what's available for your travel dates

Getting around

All Transportation Options at a Glance

City Centre
Siena 1.5 km
Airports
Peretola (FLR) 85.5 km
Galileo Galilei (PSA) 118.9 km
Train
Siena train station 3.1 km
Bus
Bus stop100 m

Amenities

Thoughtfully designed amenities for a comfortable & memorable stay

General

  • No smoking on site
  • Free Wi-Fi
  • Parking
  • Safe deposit box
  • Express check-in/ -out
  • Pets allowed
  • Rooms/ Facilities for disabled
  • Luggage storage
  • Coffee shop
  • Fire extinguishers

Services

  • Paid shuttle service
  • Tours/Ticket assistance
  • Shops/Commercial services
  • Welcome drink

Dining

  • Bar/ Lounge area
  • Picnic area/ Tables

Children

  • Cots
  • Babysitting/Child services

Spa & Leisure

  • Sun terrace
  • Garden area

Room features

  • Wi-Fi in rooms
  • Air conditioning
  • Heating
  • Mini-bar
  • Sitting area
  • Dressing area
  • Patio
  • Terrace
  • Garden furniture
  • Ironing facilities

Bathroom

  • Free toiletries

Media

  • Flat-screen TV
  • AM/FM alarm clock

Room decor

  • Parquet floor
Show more

Location

Via E. S. Piccolomini 135, Siena, Italy, 53100
Map view
Via E. S. Piccolomini 135, Siena, Italy, 53100
Nearby
Park
Ristorante
360 m
Restaurants
Trattoria Fori Porta
60 m
Via Claudio Tolomei 1 angolo Via Enea Silvio Piccolomini
Pasticceria Peccati Di Gola Di Antonino Betti
200 m
Via Enea Silvio Piccolomini 43/45
Il Kiosko Di Milkone
3.2 km
Via Massetana Romana
Bar Porta Tufi
2.2 km
Via Pier Andrea Mattioli 14/16
Ristorante
1.6 km
39 Via Porta Giustizia
Unlock Early-Bird Deals
Grab Exclusive Rates Instantly
Check Rates

Next best alternative

Consider them for your next trip.

Inspiration for future getaways

Good Hotel alternatives
Check-in
06Nov2025Select date
Check-out
07Nov2025Select date
Rooms and Guests2 Guests, 1 Room